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Merck 109671 1,4-Dioxane for analysis EMSURE® ACS,ISO 2.5 L

Marka
Stok Kodu
LB.M.1096712500
Kısa Bilgi
Synonym(s): 1,4-Dioxane, Glycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane Empirical Formula (Hill Notation): C4H8O2 CAS Number: 123-91-1 Molecular Weight: 88.11 MDL number: MFCD00006571 EC Index Number: 204-661-8
Merck 109671 1,4-Dioxane for analysis EMSURE® ACS,ISO 2.5 L
Catalogue Number 109671
Synonyms Glycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane
Overview EMSURE® grade solvents are suitable for a broad spectrum of classical lab applications, and are frequently used in regulated and highly demanding lab applications. EMSURE® provides worldwide best and most extensive product specifications. We declare our EMSURE® range to be in compliance with the ACS, with the reagent part of the European Pharmacopoeia (Reag. Ph Eur) and also with the ISO standards.
Merck 109671 1,4-Dioxane for analysis EMSURE® ACS,ISO 
Product Information
CAS number 123-91-1
EC index number 603-024-00-5
EC number 204-661-8
Grade ACS,ISO
Hill Formula C₄H₈O₂
Molar Mass 88.11 g/mol
HS Code 2932 99 00
Structure formula Image Structure formula Image
Quality Level MQ300
Physicochemical Information
Boiling point 101.5 °C (1013 hPa)
Density 1.034 g/cm3 (20 °C)
Explosion limit 1.7 - 25.2 %(V)
Flash point 11 °C
Ignition temperature 300 °C
Melting Point 11.8 °C
pH value 6.0 - 8 (500 g/l, H₂O, 20 °C)
Vapor pressure 36 hPa (20 °C)
Toxicological Information
LD 50 oral LD50 Rat 5200 mg/kg
LD 50 dermal LD50 Rabbit 7600 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s) H225: Highly flammable liquid and vapour.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H350: May cause cancer.
EUH019: May form explosive peroxides.
EUH066: Repeated exposure may cause skin dryness or cracking.
Precautionary Statement(s) P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P240: Ground and bond container and receiving equipment.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Signal Word Danger
RTECS JG8225000
Storage class 3 Flammable liquids
WGK WGK 2 obviously hazardous to water
Disposal 3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Safety Information
Categories of danger highly flammable, irritant, carcinogenic
Storage and Shipping Information
Storage Store at +2°C to +30°C.
Transport Information
Declaration (railroad and road) ADR, RID UN 1165 , 3, II
Declaration (transport by air) IATA-DGR UN 1165 , 3, II
Declaration (transport by sea) IMDG-Code UN 1165 , 3, II
Specifications
Purity (GC) ≥ 99.5 %
Identity (IR) conforms
Color ≤ 10 Hazen
Acidity ≤ 0.0008 meq/g
Density (d 20 °C/ 4 °C) 1.030 - 1.035
Melting point ≥ 11.0 °C
Formaldehyde ≤ 0.05 %
Acetaldehyde ≤ 0.005 %
Peroxide (as H₂O₂) ≤ 0.005 %
Carbonyl compounds (as CO) ≤ 0.01 %
Evaporation residue ≤ 0.001 %
Water ≤ 0.05 %
Al (Aluminium) ≤ 0.00005 %
B (Boron) ≤ 0.000002 %
Ba (Barium) ≤ 0.00001 %
Ca (Calcium) ≤ 0.00005 %
Cd (Cadmium) ≤ 0.000005 %
Co (Cobalt) ≤ 0.000002 %
Cr (Chromium) ≤ 0.000002 %
Cu (Copper) ≤ 0.000002 %
Fe (Iron) ≤ 0.00001 %
Mg (Magnesium) ≤ 0.00001 %
Mn (Manganese) ≤ 0.000002 %
Ni (Nickel) ≤ 0.000002 %
Pb (Lead) ≤ 0.00001 %
Sn (Tin) ≤ 0.00001 %
Zn (Zinc) ≤ 0.00001 %
Stabilized with 25 ppm 2,6-Di-tert-butyl-4-methylphenol (BHT).
ACS, ISO-reagent
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Merck 109671 1,4-Dioxane for analysis EMSURE® ACS,ISO
Merck 109671 1,4-Dioxane for analysis EMSURE® ACS,ISO 2.5 L Synonym(s): 1,4-Dioxane, Glycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane, Empirical Formula (Hill Notation): C4H8O2, CAS Number: 123-91-1 LB.M.1096712500
Merck 109671 1,4-Dioxane for analysis EMSURE® ACS,ISO 2.5 L

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