Sınırlı Stok
Sigma Aldrich 146498 Trimethyltin chloride 50 gr
Kategori
Marka
Stok Kodu
LB.SA.146498-50G
Kısa Bilgi
Synonym(s): Chlorotrimethylstannane Linear Formula: (CH3)3SnCl CAS Number: 1066-45-1 Molecular Weight: 199.27 Beilstein: 3535111 EC Number: 213-917-8 MDL number: MFCD00000520 UNSPSC Code: 12352103 PubChem Substance ID: 24848783 NACRES: NA.22
Bilgi
CAS Number: 1066-45-1
| Sigma Aldrich 146498 Trimethyltin chloride 50 gr |
| Synonym(s): Chlorotrimethylstannane Linear Formula: (CH3)3SnCl CAS Number: 1066-45-1 Molecular Weight: 199.27 Beilstein: 3535111 EC Number: 213-917-8 MDL number: MFCD00000520 UNSPSC Code: 12352103 PubChem Substance ID: 24848783 NACRES: NA.22 |
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PROPERTIES
form crystals
Quality Level 100 mp 37-39 °C (lit.) SMILES string C[Sn](C)(C)Cl InChI 1S/3CH3.ClH.Sn/h3*1H3;1H;/q;;;;+1/p-1 InChI key KWTSZCJMWHGPOS-UHFFFAOYSA-M DESCRIPTION General description Trimethyltin chloride is an organotin reagent widely used in transferring trimethylstannyl groups onto the substrates to synthesize various organostannanes. Trimethylstannyl compounds derived from this reagent, are extensively used in the palladium-catalyzed Stille coupling reactions. Application Trimethyltin chloride can be used as a precursor to synthesize trimethyltin hydride, cyanide, methoxide, azide, and lithium compounds.[1] It can also be used as a reagent to prepare: - Organotrimethyltin derivatives by reacting with organocopper compounds via transmetalation reaction.[1] - Acetophenone by palladium-catalyzed coupling reaction with benzoyl chloride.[1] - Optically active propargyl trimethylstannane by treating with chiral allenyltitanium.[1] - Trimethylstannyl nucleophiles, which are applicable in the formation of Sn-C bonds via SN2 reactions, SRN1 reactions, and halogen-metal exchanges.[1] - Carbocycles by reacting with unactivated dienes or trienes via radical-mediated carbocyclization reaction in the presence of NaBH3CN and a catalytic amount of AIBN.[1] Me3SnCl can also be used as a Lewis acid catalyst in asymmetric allylic alkylation reactions.[1] |
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