Sigma-Aldrich 214000 TEMPO 98% 25 gr
Marka
Stok Kodu
LB.SA.214000-25G
Kısa Bilgi
Synonym(s): 2,2,6,6-Tetramethylpiperidine 1-oxyl, 2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical, TEMPO Empirical Formula (Hill Notation): C9H18NO CAS Number: 2564-83-2 Molecular Weight: 156.25 Beilstein: 1422418 EC Number: 219-888-8 MDL number: MFCD00009599 PubChem Substance ID: 24852819
Garanti Süresi
24 Ay
| Sigma-Aldrich 214000 TEMPO 98% 25 gr |
|
Synonym(s): 2,2,6,6-Tetramethylpiperidine 1-oxyl, 2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical, TEMPO
Empirical Formula (Hill Notation): C9H18NO
CAS Number: 2564-83-2
Molecular Weight: 156.25
Beilstein: 1422418
EC Number: 219-888-8
MDL number: MFCD00009599
PubChem Substance ID: 24852819 |
|
PROPERTIES
Quality Level 200
Assay 98%
form solid
reaction suitability reagent type: oxidant
greener alternative product characteristics Catalysis
mp 36-38 °C (lit.)
greener alternative category Aligned
storage temp. 2-8°C
SMILES string CC1(C)CCCC(C)(C)N1[O]
InChI 1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3
InChI key QYTDEUPAUMOIOP-UHFFFAOYSA-N
DESCRIPTION
General description
Copper/TEMPO has been utilized in the catalytic oxidation of primary alcohols to aldehydes.[1]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.
Application
TEMPO can be used:
As a catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.
As a catalytic oxidant in the iodobenzene diacetae oxidation of nerol to neral.[2]
For trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene.[3]
In the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.[4] |
