Hoşgeldiniz
Hızlı ve Güvenli Alışverişe Giriş Yapın!
Üye Değil misiniz?
Kolayca Üye Olabilirsiniz.

Sigma-Aldrich 34660 Di-tert-butyl dicarbonate ≥98.0% (GC) 25 gr

Stok Kodu
LB.SA.34660-25G-F
Kısa Bilgi
Synonym(s): Boc2O, Boc anhydride, Di-tert-butyl pyrocarbonate Linear Formula: [(CH3)3COCO]2O CAS Number: 24424-99-5 Molecular Weight: 218.25 Beilstein: 1911173 EC Number: 246-240-1 MDL number: MFCD00008805 PubChem Substance ID: 329755051 NACRES: NA.22
Sigma-Aldrich 34660 Di-tert-butyl dicarbonate ≥98.0% (GC) 25 gr
Synonym(s): Boc2O, Boc anhydride, Di-tert-butyl pyrocarbonate
Linear Formula: [(CH3)3COCO]2O
CAS Number: 24424-99-5
Molecular Weight: 218.25
Beilstein: 1911173
EC Number: 246-240-1
MDL number: MFCD00008805
PubChem Substance ID: 329755051
NACRES: NA.22
Sigma-Aldrich 34660 Di-tert-butyl dicarbonate ≥98.0% (GC)
PROPERTIES
Quality Level 200 
Assay ≥98.0% (GC)
form solid or liquid 
refractive index n20/D 1.409 (lit.) 
bp 56-57 °C/0.5 mmHg (lit.) 
mp 23 °C (lit.) 
density 0.95 g/mL at 25 °C (lit.) 
application(s) peptide synthesis 
storage temp. 2-8°C 
SMILES string CC(C)(C)OC(=O)OC(=O)OC(C)(C)C 
InChI 1S/C10H18O5/c1-9(2,3)14-7(11)13-8(12)15-10(4,5)6/h1-6H3 
InChI key DYHSDKLCOJIUFX-UHFFFAOYSA-N
 
DESCRIPTION  
General description
Di-tert-butyl dicarbonate (Boc2O) is a reagent mainly used for the introduction of the Boc protecting group to amine functionalities. It is also used as a dehydrating agent in some organic reactions, particularly with carboxylic acids, certain hydroxyl groups, or with primary nitroalkanes.
Application
Di-tert-butyl dicarbonate (Boc2O) has been used in the synthesis of:
- An azobenzene amino acid(aa).
- N-tert-butoxycarbonyl-3,4-methylenedioxymethamphetamine (t-BOC-MDMA) from MDMA.
It can also be used as a reagent:
- To introduce acid-labile Boc-protecting group in amino acids, peptides, and proteins.     
- To prepare styrene derivatives by Heck olefination of aromatic carboxylic acids in the presence of a Pd catalyst.     
- To synthesize oxazolidin-2-ones and imidazolidin-2-ones by isocyanation of 1,2-aminoalcohols and 1,2-diamines using DMAP as a catalyst.    
- In the preparation of N-tert-butoxycarbonyl-3,4-methylenedioxymethamphetamine (t-Boc-MDMA) from MDMA.
- For the conversion of amines to corresponding isocyanates, carbamates, and urea derivatives.
- In the N-BOC-ylation of amides.
- In the N-BOC-ylation of sensitive compounds under non-aqueous conditions.
- Reagent for the introduction of the Boc protecting group.
Packaging
25, 100, 100, 500, 500 g
1, 10, 25 kg
Warning
Hydrolyzes to t-butanol and CO2; causes internal pressure in bottle if exposed to moisture.
Bu ürünün fiyat bilgisi, resim, ürün açıklamalarında ve diğer konularda yetersiz gördüğünüz noktaları öneri formunu kullanarak tarafımıza iletebilirsiniz.
Görüş ve önerileriniz için teşekkür ederiz.
Sigma-Aldrich 34660 Di-tert-butyl dicarbonate ≥98.0% (GC)
Sigma-Aldrich 34660 Di-tert-butyl dicarbonate ≥98.0% (GC) 25 gr Synonym(s): Boc2O, Boc anhydride, Di-tert-butyl pyrocarbonate, Linear Formula: [(CH3)3COCO]2O, CAS Number: 24424-99-5, Molecular Weight: 218.25, Beilstein: 1911173, EC Number: 246-240-1 LB.SA.34660-25G-F
Sigma-Aldrich 34660 Di-tert-butyl dicarbonate ≥98.0% (GC) 25 gr

Tavsiye Et

*
*
*
IdeaSoft® | E-Ticaret paketleri ile hazırlanmıştır.