Sigma-Aldrich 447536 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane 1 gr
Marka
Stok Kodu
LB.SA.447536-1G
Kısa Bilgi
95% Synonym(s): Tetramethylethylene chlorophosphite Empirical Formula (Hill Notation): C6H12ClO2P CAS Number: 14812-59-0 Molecular Weight: 182.59 MDL number: MFCD00274239 PubChem Substance ID: 24868346 NACRES: NA.22
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Sigma-Aldrich 447536 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane 1 gr |
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Synonym(s): Tetramethylethylene chlorophosphite
Empirical Formula (Hill Notation): C6H12ClO2P
CAS Number: 14812-59-0
Molecular Weight: 182.59
MDL number: MFCD00274239
PubChem Substance ID: 24868346
NACRES: NA.22 |
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PROPERTIES
Assay 95%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand refractive index n20/D 1.471 (lit.)
bp 81.5-82 °C/13 mmHg (lit.)
density 1.149 g/mL at 25 °C (lit.)
SMILES string CC1(C)OP(Cl)OC1(C)C
InChI 1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3
InChI key WGPCXYWWBFBNSS-UHFFFAOYSA-N
DESCRIPTION
Application
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane (TMDP) can be used:
As a reagent for the phosphitylation of alcohols and heteroatomic nucleophiles, resulting in the formation of useful glycosyl donors and ligands.[1][2]
As a phosphitylation reagent to derivatize lignin samples for 31P NMR analysis.[3][4][5] |
