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Sigma-Aldrich 523216 Methacryloyl chloride 97%, contains ~200 ppm monomethyl ether hydroquinone as stabilizer 100 mL

Stok Kodu
LB.SA.523216-100ML
Kısa Bilgi
Linear Formula: CH2=C(CH3)COCl CAS Number: 920-46-7 Molecular Weight: 104.53 Beilstein: 878175 EC Number: 213-058-9 MDL number: MFCD00000716 UNSPSC Code: 12162002 PubChem Substance ID: 24874306 NACRES: NA.23
Bilgi
CAS Number: 920-46-7
Ön Siparişli Ürün
Sigma-Aldrich 523216 Methacryloyl chloride 97%, contains ~200 ppm monomethyl ether hydroquinone as stabilizer 
Synonym(s): α-Methylacryloyl chloride, 2-Methyl-2-propenoyl chloride, 2-Methylacryloyl chloride, 2-Methylpropenoic acid chloride, Methacrylic acid chloride, Methacrylic chloride 
Linear Formula: CH2=C(CH3)COCl
CAS Number: 920-46-7
Molecular Weight: 104.53
Beilstein: 878175
EC Number: 213-058-9
MDL number: MFCD00000716
UNSPSC Code: 12162002
PubChem Substance ID: 24874306
NACRES: NA.23
Sigma-Aldrich R0901 RNAlater® Stabilize and protect RNA with immediate RNase inactivation 100 mL     
PROPERTIES
Quality Level 200
Assay
97%
contains
~200 ppm monomethyl ether hydroquinone as stabilizer
refractive index
n20/D 1.442 (lit.)
bp
95-96 °C (lit.)
density
1.07 g/mL at 25 °C (lit.)
storage temp
. −20°C
SMILES string
CC(=C)C(Cl)=O
InChI
1S/C4H5ClO/c1-3(2)4(5)6/h1H2,2H3
InChI key
VHRYZQNGTZXDNX-UHFFFAOYSA-N


DESCRIPTION

General description
Methacryloyl chloride is the clear to slightly colored acid chloride of methacrylic acid. Monomethyl ether hydroquinone is added as a stabilizer to prevent auto polymerization. Reaction with diisopropyl ether in presence of metal salts is rigorous.
Application
Methacryloyl chloride is used in the manufacture of polymers:
- Monomer 2-methacrylamido-caprolactam was prepared by reacting methacryloyl chloride with racemic a-amino-e-caprolactam.[1]
- Functional monomer was prepared by reacting methacryloyl chloride and L-histidine.[2]
- A series of amide monomers were synthesized by amidation of methacryloyl chloride with amines and grafted onto commercial poly(ether sulfone) (PES) membranes using irradiation from atmospheric pressure plasma (APP).[3]
- Reaction of methacryloyl chloride with the hydroxyl groups on the surfaces of HEMA/NVP microspheres was performed, leading to the introduction of polymerisable double bonds onto the surfaces of microspheres.[4]
- Star-shaped poly(d,l-lactide) oligomers with 2, 3 and 6 arms were synthesised, end-functionalised with methacryloyl chloride and photo-crosslinked in the presence of ethyl lactate as a non-reactive diluent.[5]
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Sigma-Aldrich 523216 Methacryloyl chloride 97%, contains ~200 ppm monomethyl ether hydroquinone as stabilizer 100 mL Linear Formula: CH2=C(CH3)COCl CAS Number: 920-46-7 Molecular Weight: 104.53 Beilstein: 878175 EC Number: 213-058-9 MDL number: MFCD00000716 UNSPSC Code: 12162002 PubChem Substance ID: 24874306 NACRES: NA.23 LB.SA.523216-100ML
Sigma-Aldrich 523216 Methacryloyl chloride 97%, contains ~200 ppm monomethyl ether hydroquinone as stabilizer 100 mL

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