Sigma-Aldrich 87368 Tetrahydrofuran contains 250 ppm BHT as inhibitor, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.9% 1 L
Kategori
Marka
Stok Kodu
LB.SA.87368-1L
Kısa Bilgi
Synonym(s): Butylene oxide, Oxolane, Tetramethylene oxide Empirical Formula (Hill Notation): C4H8O CAS Number: 109-99-9 Molecular Weight: 72.11 Beilstein: 102391 EC Number: 203-726-8 MDL number: MFCD00005356 PubChem Substance ID: 329769580
| Sigma-Aldrich 87368 Tetrahydrofuran |
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Synonym(s): Butylene oxide, Oxolane, Tetramethylene oxide
Empirical Formula (Hill Notation): C4H8O
CAS Number: 109-99-9
Molecular Weight: 72.11
Beilstein: 102391 EC Number: 203-726-8
MDL number: MFCD00005356
PubChem Substance ID: 329769580 |
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PROPERTIES
grade
ACS reagent
puriss. p.a.
Quality Level 200
Agency reag. Ph. Eur.
vapor density 2.5 (vs air)
vapor pressure
114 mmHg ( 15 °C)
143 mmHg ( 20 °C)
Assay ≥99.9%
form liquid
autoignition temp. 610 °F
contains
250 ppm BHT as inhibitor
~0.025% 2,6-di-tert-butyl-4-methylphenol as stabilizer
expl. lim. 1.8-11.8 %
technique(s) solid phase extraction (SPE): suitable
impurities
≤0.001% free acid (as CH3COOH)
≤0.005% peroxides (as H2O2)
≤0.05% water
evapn. residue ≤0.001%
refractive index n20/D 1.407 (lit.) n20/D 1.407
pH ~7
bp 65-67 °C (lit.)
mp −108 °C (lit.)
density 0.887 g/mL at 20 °C 0.889 g/mL at 25 °C (lit.)
cation traces
Al: ≤0.5 mg/kg
B: ≤0.02 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sn: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg
SMILES string C1CCOC1 InChI 1S/C4H8O/c1-2-4-5-3-1/h1-4H2
InChI key WYURNTSHIVDZCO-UHFFFAOYSA-N
DESCRIPTION
General description
The product is tetrahydrofuran (THF) and it contains 250ppm BHT (Butylated hydroxytoluene) as an inhibitor. THF is widely employed as a solvent. It constitutes the key fragment of various natural products (polyether antibiotics).[1] THF forms double hydrate with hydrogen sulfide. Crystal structure of this double hydrate has been investigated by three-dimensional single-crystal studies.[2] Butane-1,4-diol is formed as an intermediate during the synthesis of THF.[3] Hot THF is useful for the dissolution of polyvinylidene chloride (PVDV).[4]
Application
Tetrahydrofuran has been used as a solvent for the preparation of sol-gel solution for coating solid phase microextraction (SPME) fibers in a study.[5] It may be used for the dissolution of poly-ε-caprolactone (PCL) and 1,3-diaminopentane, during the preparation of poly-ε-caprolactone (PCL)-hydroxyapatite (HA) scaffolds[6] and acrylate-terminated poly(5-amino-1-pentanol-co-1,4-butanediol diacrylate) (C32)- 1,3-diaminopentane (117) polymer,[7] respectively.
Analysis Note
miscible with water and ethanol (96%) pass |
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