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Sigma-Aldrich D158550 N,N-Dimethylformamide ReagentPlus®, ≥99% 1 L

Kategori
Stok Kodu
LB.SA.D158550-1L
Kısa Bilgi
Synonym(s): DMF, NSC 5356 Linear Formula: HCON(CH3)2 CAS Number: 68-12-2 Molecular Weight: 73.09 Beilstein: 605365 EC Number: 200-679-5 MDL number: MFCD00003284 PubChem Substance ID: 329798705 NACRES: NA.21
Bilgi
CAS Number: 68-12-2
Ön Siparişli Ürün
Sigma-Aldrich D158550 N,N-Dimethylformamide ReagentPlus®, ≥99% 
Synonym(s): DMF, NSC 5356
Linear Formula:
HCON(CH3)2
CAS Number
: 68-12-2
Molecular Weight:
73.09
Beilstein:
605365
EC Number:
200-679-5
MDL number:
MFCD00003284
PubChem Substance ID:
329798705
NACRES:
NA.21
Sigma-Aldrich D158550 N,N-Dimethylformamide ReagentPlus®, ≥99%     
PROPERTIES
vapor density 2.5 (vs air)
Quality Level
100
vapor pressure
2.7 mmHg ( 20 °C)
product line
ReagentPlus®
Assay
≥99%
form
liquid
autoignition temp.
833 °F
expl. lim.
15.2 %
impurities
≤0.1% Water (Karl Fischer)
refractive index
n20/D 1.430 (lit.)
pH
6.7
bp
153 °C (lit.)
mp
−61 °C (lit.)
density
0.944 g/mL (lit.)
SMILES string
[H]C(=O)N(C)C
InChI
1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3
InChI key
ZMXDDKWLCZADIW-UHFFFAOYSA-N


DESCRIPTION
General description
N,N-Dimethylformamide (DMF) is a polar organic solvent with a wide range of industrial applications.[1] It is a precursor for numerous reactions such as formylation, aminocarbonylation, amination, amidation and cyanation.[2] Along with phosphorus oxychloride, it forms Vilsmeier reagent used in the formylation of reactive aromatic and heteroaromatic substrates.[3] Dielectric relaxation experiments on DMF have been conducted between 238.15 K and 338.15K.[4] The thermophysical properties of the molecular interactions between DMF and the ionic liquids, ammonium salts and imidazolium salts have been studied.[5] The characteristics of solute-solvent interactions between ammonium nitrate and DMF have been investigated.[6]
Application
N,N-Dimethylformamide has been used in the to prepare pure polyurethane as well as nanocomposite solutions. It may be used in the following processes:
- Synthesis of gold nanoparticles.[7]
- Capillary electrophoresis.[8]
- Regioselective synthesis of N,N-dimethylaminopyridzines.[9]
- Synthesis of urea-N,N-dimethylformamide, a 3:1 solvate with urea.[10]
Solvent for many hydrophobic organic compounds.
Other Notes
A Greener alternative is available for many DMF applications, Cyrene (807796)
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany+

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Sigma-Aldrich D158550 N,N-Dimethylformamide ReagentPlus®, ≥99% 1 L Linear Formula: HCON(CH3)2, CAS Number: 68-12-2, Molecular Weight: 73.09, Beilstein: 605365, EC Number: 200-679-5, MDL number: MFCD00003284, PubChem Substance ID: 329798705, NACRES: NA.21 LB.SA.D158550-1L
Sigma-Aldrich D158550 N,N-Dimethylformamide ReagentPlus®, ≥99% 1 L

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