Sigma-Aldrich T32808 Thiophenol 97% 500 gr
Marka
Stok Kodu
LB.SA.T32808-500G
Kısa Bilgi
Synonym(s): Benzenethiol, Phenyl mercaptan Linear Formula: C6H5SH CAS Number: 108-98-5 Molecular Weight: 110.18 Beilstein: 506523 EC Number: 203-635-3 MDL number: MFCD00004826 PubChem Substance ID: 24900127 NACRES: NA.22
| Sigma-Aldrich T32808 Thiophenol 97% 500 gr |
| Synonym(s): Benzenethiol, Phenyl mercaptan Linear Formula: C6H5SH CAS Number: 108-98-5 Molecular Weight: 110.18 Beilstein: 506523 EC Number: 203-635-3 MDL number: MFCD00004826 PubChem Substance ID: 24900127 NACRES: NA.22 |
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PROPERTIES
vapor density 3.8 (vs air)
Quality Level 100 vapor pressure 1.4 mmHg ( 20 °C) Assay 97% refractive index n20/D 1.588 (lit.) bp 169 °C (lit.) mp −15 °C (lit.) density 1.073 g/mL at 25 °C (lit.) SMILES string Sc1ccccc1 InChI 1S/C6H6S/c7-6-4-2-1-3-5-6/h1-5,7H InChI key RMVRSNDYEFQCLF-UHFFFAOYSA-N DESCRIPTION General description Thiophenol is an organosulfur compound used as an intermediate to produce polymers.[1] Application Thiophenol can undergo: Asymmetric Michael addition to diisopropyl maleate in the presence of a catalytic amount of cinchonine to form (s)-(−)-diisopropyl phenylthiosuccinate, which can be further converted to (R)-(+)-3,4-epoxy-1-butanol.[2] Regioselective and stereoselective 1,4-addition to alkenylidenecyclopropanes leading to endo- or cis-vinyl sulfide adducts, a key step in the synthesis of karahanaenone.[3] Diastereoselective addition to (S)-N-(α,β-unsaturated carbonyl)-γ-[(trityloxy)methyl]-γ-butyrolactams to form the corresponding β-(phenylthio)carboxylates.[4] |
